Reversible encapsulation of xenon and CH2Cl2 in a solid-state molecular organometallic framework (Guest@SMOM)
Reversible encapsulation of CH 2 Cl 2 or Xe in a non–porous solid–state molecular organometallic framework of [Rh(Cy 2 PCH 2 PCy 2 )(NBD)][BAr F 4 ] occurs in single–crystal to single–crystal transformations. These processes are also probed by solid–state NMR spectroscopy, including 129 Xe SSNMR. N...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Wiley
2019
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| Summary: | Reversible encapsulation of CH 2 Cl 2 or Xe in a non–porous solid–state molecular organometallic framework of [Rh(Cy 2 PCH 2 PCy 2 )(NBD)][BAr F 4 ] occurs in single–crystal to single–crystal transformations. These processes are also probed by solid–state NMR spectroscopy, including 129 Xe SSNMR. Non–covalent interactions with the –CF 3 groups, and hydrophobic channels formed, of [BAr F 4 ] – anions are shown to be important, and thus have similarly to the transport of substrates and products to and from the active site in metalloenzymes. |
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