Atmospheric chemistry of CF3CH2OCHF2 and CF3CHClOCHF2: Kinetics and mechanisms of reaction with Cl atoms and OH radicals and atmospheric fate of CF3C(O center dot)HOCHF2 and CF3C(O center dot)ClOCHF2 radicals

Atmospheric chemistry of CF3CH2OCHF2 and CF3CHClOCHF2: Kinetics and mechanisms of reaction with Cl atoms and OH radicals and atmospheric fate of CF3C(O center dot)HOCHF2 and CF3C(O center dot)ClOCHF2 radicals

Relative rate techniques were used to measure k(Cl + CF3CH2OCHF2) = (1.2 ± 0.1) × 10-14, k(Cl + CF3CHClOCHF2) = (5.4 ± 0.5) × 10-15, k(Cl + HC(O)OCHF2) = (2.0 ± 0.2) × 10-14, and k(Cl + CF3C(O)OCHF2) < 4 × 10-17 cm3 molecule-1 s-1 at 295 K. Cl atoms react with CF3CHClOCHF2 (isoflurane, HCFE-2...

Mô tả đầy đủ

Chi tiết về thư mục
Những tác giả chính:	Wallington, T, Hurley, MD, Fedotov, V, Morrell, C, Hancock, G
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	2002

Những quyển sách tương tự

Computer-simulated degradation of CF3Cl, CF2Cl2, and CFCl3 under electron beam irradiation
Bằng: Kabasa Stephen, et al.
Được phát hành: (2023-07-01)

Diversity-oriented approach to CF3CHF-, CF3CFBr-, CF3CF2-, (CF3)2CH-, and CF3(SCF3)CH-substituted arenes from 1-(diazo-2,2,2-trifluoroethyl)arenes.
Bằng: Emer, E, et al.
Được phát hành: (2014)

LASER-INDUCED FLUORESCENCE DETECTION OF CF AND CF2 RADICALS IN A CF4/O2 PLASMA
Bằng: Booth, J, et al.
Được phát hành: (1987)

CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation and chlorination. Part 2: Use of CF3SO2Cl
Bằng: Hélène Chachignon, et al.
Được phát hành: (2017-12-01)

SPATIALLY AND TEMPORALLY RESOLVED LASER-INDUCED FLUORESCENCE MEASUREMENTS OF CF2 AND CF RADICALS IN A CF4 RF PLASMA
Bằng: Booth, J, et al.
Được phát hành: (1989)

Why •CF2H is nucleophilic but •CF3 is electrophilic in reactions with heterocycles
Bằng: Meng Duan, et al.
Được phát hành: (2024-05-01)

Tropospheric photooxidation of CF<sub>3</sub>CH<sub>2</sub>CHO and CF<sub>3</sub>(CH<sub>2</sub>)<sub>2</sub>CHO initiated by Cl atoms and OH radicals
Bằng: J. Albaladejo, et al.
Được phát hành: (2010-02-01)

CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na
Bằng: Hélène Guyon, et al.
Được phát hành: (2017-12-01)

Copper-Mediated −CF(OCF3)(CF2H) Transfer to Organic Electrophiles
Bằng: Behnaz Ghaffari, et al.
Được phát hành: (2024-09-01)

Measurement report: Radiative efficiencies of (CF<sub>3</sub>)<sub>2</sub>CFCN, CF<sub>3</sub>OCFCF<sub>2</sub>, and CF<sub>3</sub>OCF<sub>2</sub>CF<sub>3</sub>
Bằng: B. A. Trisna, et al.
Được phát hành: (2023-04-01)

The [3+2] Annulation of CF3-Ketimines by Re Catalysis: Access to CF3-Containing Amino Heterocycles and Polyamides
Bằng: Saisai Zhang, et al.
Được phát hành: (2020-11-01)

Infrared emission from the CF3+NO2 reaction
Bằng: Oum, K, et al.
Được phát hành: (1997)

The synthesis and characterisation of some Group 14 compounds containing the 2,4,6-(CF3)(3)C6H2, 2,6-(CF3)(2)C6H3 or 2,4-(CF3)(2)C6H3 ligands
Bằng: Batsanov, A, et al.
Được phát hành: (2003)

Redox chemistry of trifluoromethyl sulfonium salts as CF3 radical sources
Bằng: Mizuta, S, et al.
Được phát hành: (2013)

PhI(OAc)2 mediated radical trifluoromethylation of vinyl azides with Me3SiCF3
Bằng: Wang, Yi-Feng, et al.
Được phát hành: (2014)

Study of MgO transformation into MgF2 in the presence of CF2Cl2•
Bằng: Vedyagin Aleksey A., et al.
Được phát hành: (2017-01-01)

Effects of hydrophobic chain structure on adsorption of fluorocarbon surfactants with either CF3- or H-CF2-terminal groups
Bằng: Downer, A, et al.
Được phát hành: (1999)

An Efficient Synthesis of 2-CF<sub>3</sub>-3-Benzylindoles
Bằng: Vasiliy M. Muzalevskiy, et al.
Được phát hành: (2021-08-01)

New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands
Bằng: Batsanov, A, et al.
Được phát hành: (2002)

Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)(3)C6H2 (fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar '), or 2,4-(CF3)(2)C6H3 (Ar '') ligands
Bằng: Cornet, S, et al.
Được phát hành: (2003)

SERCA2 regulates non-CF and CF airway epithelial cell response to ozone.
Bằng: Shama Ahmad, et al.
Được phát hành: (2011-01-01)

Fluorinated nonionic surfactants bearing either CF3- or H-CF2- terminal groups: Adsorption at the surface of aqueous solutions
Bằng: Eastoe, J, et al.
Được phát hành: (2001)

Ionic Association in CH3–(CH2–CF2)n–CH3(PVDF)–Li+–(CF3SO2)2N– for n = 1, 4: A Computational Approach
Bằng: Mathew Daniel, et al.
Được phát hành: (2022-02-01)

Atmospheric chemistry of trans-CF3CH=CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation
Bằng: T. J. Wallington, et al.
Được phát hành: (2008-06-01)

Synthesis and Reactions of 3-Halogenated 2-CF<sub>3</sub>-Indoles
Bằng: Vasiliy M. Muzalevskiy, et al.
Được phát hành: (2022-12-01)

THE STRUCTURE OF SOLID CF3I
Bằng: Clarke, S, et al.
Được phát hành: (1993)

Deuteriodifluoromethylation and gem‐Difluoroalkenylation of Aldehydes Using ClCF2H in Continuous Flow
Bằng: Fu, Wai Chung, et al.
Được phát hành: (2020)

CfA3: 185 TYPE Ia SUPERNOVA LIGHT CURVES FROM THE CfA
Bằng: Krauss, Miriam, et al.
Được phát hành: (2015)

Synthesis and Reactivity of Mn–CF3 Complexes
Bằng: Alex L. Daniels, et al.
Được phát hành: (2019-01-01)

Pathogenesis, imaging and clinical characteristics of CF and non-CF bronchiectasis
Bằng: Schäfer, Jürgen, et al.
Được phát hành: (2018)

Pathogenesis, imaging and clinical characteristics of CF and non-CF bronchiectasis
Bằng: Jürgen Schäfer, et al.
Được phát hành: (2018-05-01)

THE RADIATIVE LIFETIME OF CF(A2SIGMA+)
Bằng: Booth, J, et al.
Được phát hành: (1988)

BrCF2CN for photocatalytic cyanodifluoromethylation
Bằng: Xin-Jun Yang, et al.
Được phát hành: (2025-01-01)

Study on suppression of CH4 explosion by CF3H and CO2
Bằng: Jieqi BAI, et al.
Được phát hành: (2024-05-01)

CF2H-synthon enables asymmetric radical difluoroalkylation for synthesis of chiral difluoromethylated amines
Bằng: Peng Liu, et al.
Được phát hành: (2025-01-01)

The Metamorphosis of Mg(SO3CF3)2‐based Electrolytes for Rechargeable Magnesium Batteries
Bằng: Dr. Jinlong Chen, et al.
Được phát hành: (2024-04-01)

Geological hazard susceptibility evaluation based on CF and CF-LR model
Bằng: Shuiyun TU, et al.
Được phát hành: (2022-04-01)

Impact of vitamin D status on CF and non-CF bronchiectasis outcomes
Bằng: Heba A. Ali, et al.
Được phát hành: (2022-01-01)

The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes
Bằng: Aziz, M., et al.
Được phát hành: (2006)

Chasing an Elusive Alkoxide: Attempts to Synthesize [OC(tBu)(CF3)2]?
Bằng: Lutz O. Müller, et al.
Được phát hành: (2006-04-01)