Towards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xylulose
Microbial oxidation of 2-C-methyl-d-ribitol and 2-C-methyl-d-arabinitol by Gluconobacter thailandicus NBRC 3254 produces 4-C-methyl-l-ribulose and 4-C-methyl-d-ribulose, respectively. Further, 4-C-methyl-l-ribulose and 4-C-methyl-d-ribulose were equilibrated by d-tagatose-3-epimerase (DTE) with 4-C-...
| Main Authors: | , , , , , , , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2008
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| _version_ | 1826259816058716160 |
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| author | Rao, D Yoshihara, A Gullapalli, P Morinioto, K Takata, G da Cruz, F Jenkinson, S Wormald, M Dwek, R Fleet, G Izumori, K |
| author_facet | Rao, D Yoshihara, A Gullapalli, P Morinioto, K Takata, G da Cruz, F Jenkinson, S Wormald, M Dwek, R Fleet, G Izumori, K |
| author_sort | Rao, D |
| collection | OXFORD |
| description | Microbial oxidation of 2-C-methyl-d-ribitol and 2-C-methyl-d-arabinitol by Gluconobacter thailandicus NBRC 3254 produces 4-C-methyl-l-ribulose and 4-C-methyl-d-ribulose, respectively. Further, 4-C-methyl-l-ribulose and 4-C-methyl-d-ribulose were equilibrated by d-tagatose-3-epimerase (DTE) with 4-C-methyl-l-xylulose and 4-C-methyl-d-xylulose, respectively. These transformations demonstrate that polyol dehydrogenase and DTE act on branched synthetic sugars. The green preparation of all of the stereoisomers of 4-C-methyl pentuloses illustrates the ability of biotechnology to generate novel branched monosaccharides. © 2008 Elsevier Ltd. All rights reserved. |
| first_indexed | 2024-03-06T18:55:46Z |
| format | Journal article |
| id | oxford-uuid:11c87647-8f07-4ab2-86fa-db44dba23e50 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:55:46Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:11c87647-8f07-4ab2-86fa-db44dba23e502022-03-26T10:04:09ZTowards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xyluloseJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:11c87647-8f07-4ab2-86fa-db44dba23e50EnglishSymplectic Elements at Oxford2008Rao, DYoshihara, AGullapalli, PMorinioto, KTakata, Gda Cruz, FJenkinson, SWormald, MDwek, RFleet, GIzumori, KMicrobial oxidation of 2-C-methyl-d-ribitol and 2-C-methyl-d-arabinitol by Gluconobacter thailandicus NBRC 3254 produces 4-C-methyl-l-ribulose and 4-C-methyl-d-ribulose, respectively. Further, 4-C-methyl-l-ribulose and 4-C-methyl-d-ribulose were equilibrated by d-tagatose-3-epimerase (DTE) with 4-C-methyl-l-xylulose and 4-C-methyl-d-xylulose, respectively. These transformations demonstrate that polyol dehydrogenase and DTE act on branched synthetic sugars. The green preparation of all of the stereoisomers of 4-C-methyl pentuloses illustrates the ability of biotechnology to generate novel branched monosaccharides. © 2008 Elsevier Ltd. All rights reserved. |
| spellingShingle | Rao, D Yoshihara, A Gullapalli, P Morinioto, K Takata, G da Cruz, F Jenkinson, S Wormald, M Dwek, R Fleet, G Izumori, K Towards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xylulose |
| title | Towards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xylulose |
| title_full | Towards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xylulose |
| title_fullStr | Towards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xylulose |
| title_full_unstemmed | Towards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xylulose |
| title_short | Towards the biotechnological isomerization of branched sugars: D-tagatose-3-epimerase equilibrates both enantiomers of 4-C-methyl-ribulose with both enantiomers of 4-C-methyl-xylulose |
| title_sort | towards the biotechnological isomerization of branched sugars d tagatose 3 epimerase equilibrates both enantiomers of 4 c methyl ribulose with both enantiomers of 4 c methyl xylulose |
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