MULTICHANNEL QUANTUM-DEFECT THEORY SIMULATION OF THE ZERO-KINETIC-ENERGY PHOTOELECTRON-SPECTRUM OF H-2
The multichannel quantum defect theory (MQDT) is applied to the simulation of the v+=2 band of the zero-kinetic-energy (ZEKE) photoelectron spectrum of molecular hydrogen and also to the photoionization spectrum involving autoionizing Rydberg states in the region between the v+=1 and v+=2 thresholds...
| Autors principals: | , |
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| Format: | Journal article |
| Idioma: | English |
| Publicat: |
1994
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| Sumari: | The multichannel quantum defect theory (MQDT) is applied to the simulation of the v+=2 band of the zero-kinetic-energy (ZEKE) photoelectron spectrum of molecular hydrogen and also to the photoionization spectrum involving autoionizing Rydberg states in the region between the v+=1 and v+=2 thresholds. The results of the calculations are compared with previously reported experimental results [J. Chem. Phys. 96, 4149 (1992)]. The calculations are in very good agreement with experiment and provide quantitative confirmation of the previously proposed mechanisms for intensity perturbation. © 1994 American Institute of Physics. |
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