Reactivity of a dititanium bis(pentalene) complex toward heteroallenes and main-group element–element bonds
The reactivity of the Ti=Ti double bond in (μ,η 5 :η 5 -Pn † ) 2 Ti 2 (1; Pn † = 1,4-{Si i Pr 3 } 2 C 8 H 4 ) toward isocyanide and heteroallene substrates, and molecules featuring homonuclear bonds between main-group elements (E-E) has bee n explored. Reaction of 1 with methyl isocyanide or 1,3-N...
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| Format: | Journal article |
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American Chemical Society
2016
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