Anthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.

A simple pH probe is developed based upon the covalent chemical derivatisation of carbon particles with anthraquinone. The amperometric response of electrodes constructed from this material is examined and shown to produce a Nernstian linear response to pH from 1 to 9, over a range of temperatures f...

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Main Authors: Wildgoose, G, Pandurangappa, M, Lawrence, N, Jiang, L, Jones, T, Compton, R
Format: Journal article
Language:English
Published: 2003
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author Wildgoose, G
Pandurangappa, M
Lawrence, N
Jiang, L
Jones, T
Compton, R
author_facet Wildgoose, G
Pandurangappa, M
Lawrence, N
Jiang, L
Jones, T
Compton, R
author_sort Wildgoose, G
collection OXFORD
description A simple pH probe is developed based upon the covalent chemical derivatisation of carbon particles with anthraquinone. The amperometric response of electrodes constructed from this material is examined and shown to produce a Nernstian linear response to pH from 1 to 9, over a range of temperatures from 20 to 70 degrees C, consistent with a two-electron, two-proton electrochemical process.
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institution University of Oxford
language English
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spelling oxford-uuid:1365b07d-e2a1-4eb3-a479-53b66aee73c22022-03-26T10:13:43ZAnthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1365b07d-e2a1-4eb3-a479-53b66aee73c2EnglishSymplectic Elements at Oxford2003Wildgoose, GPandurangappa, MLawrence, NJiang, LJones, TCompton, RA simple pH probe is developed based upon the covalent chemical derivatisation of carbon particles with anthraquinone. The amperometric response of electrodes constructed from this material is examined and shown to produce a Nernstian linear response to pH from 1 to 9, over a range of temperatures from 20 to 70 degrees C, consistent with a two-electron, two-proton electrochemical process.
spellingShingle Wildgoose, G
Pandurangappa, M
Lawrence, N
Jiang, L
Jones, T
Compton, R
Anthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.
title Anthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.
title_full Anthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.
title_fullStr Anthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.
title_full_unstemmed Anthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.
title_short Anthraquinone-derivatised carbon powder: reagentless voltammetric pH electrodes.
title_sort anthraquinone derivatised carbon powder reagentless voltammetric ph electrodes
work_keys_str_mv AT wildgooseg anthraquinonederivatisedcarbonpowderreagentlessvoltammetricphelectrodes
AT pandurangappam anthraquinonederivatisedcarbonpowderreagentlessvoltammetricphelectrodes
AT lawrencen anthraquinonederivatisedcarbonpowderreagentlessvoltammetricphelectrodes
AT jiangl anthraquinonederivatisedcarbonpowderreagentlessvoltammetricphelectrodes
AT jonest anthraquinonederivatisedcarbonpowderreagentlessvoltammetricphelectrodes
AT comptonr anthraquinonederivatisedcarbonpowderreagentlessvoltammetricphelectrodes