CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES
Conformational analyses for acetyl and formyl ligands bound to transition metal auxiliaries reveal that, after considering primary stereoelectronic effects where appropriate, the conformations adopted by acetyl ligands are determined primarily by steric interactions while the corresponding formyl co...
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| Format: | Journal article |
| Language: | English |
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1990
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| _version_ | 1797054710818013184 |
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| author | Davies, S Smallridge, A |
| author_facet | Davies, S Smallridge, A |
| author_sort | Davies, S |
| collection | OXFORD |
| description | Conformational analyses for acetyl and formyl ligands bound to transition metal auxiliaries reveal that, after considering primary stereoelectronic effects where appropriate, the conformations adopted by acetyl ligands are determined primarily by steric interactions while the corresponding formyl conformations are determined primarily by dipolar and electrostatic forces. No evidence for secondary stereoelectronic effects is apparent. © 1990. |
| first_indexed | 2024-03-06T19:01:03Z |
| format | Journal article |
| id | oxford-uuid:138a9c57-67c5-43d3-92c4-98a9ca0759e4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:01:03Z |
| publishDate | 1990 |
| record_format | dspace |
| spelling | oxford-uuid:138a9c57-67c5-43d3-92c4-98a9ca0759e42022-03-26T10:14:24ZCONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:138a9c57-67c5-43d3-92c4-98a9ca0759e4EnglishSymplectic Elements at Oxford1990Davies, SSmallridge, AConformational analyses for acetyl and formyl ligands bound to transition metal auxiliaries reveal that, after considering primary stereoelectronic effects where appropriate, the conformations adopted by acetyl ligands are determined primarily by steric interactions while the corresponding formyl conformations are determined primarily by dipolar and electrostatic forces. No evidence for secondary stereoelectronic effects is apparent. © 1990. |
| spellingShingle | Davies, S Smallridge, A CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES |
| title | CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES |
| title_full | CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES |
| title_fullStr | CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES |
| title_full_unstemmed | CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES |
| title_short | CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES |
| title_sort | conformational analyses for acetyl and formyl ligands bound to transition metal auxiliaries |
| work_keys_str_mv | AT daviess conformationalanalysesforacetylandformylligandsboundtotransitionmetalauxiliaries AT smallridgea conformationalanalysesforacetylandformylligandsboundtotransitionmetalauxiliaries |