A vinyl cyclopropane ring expansion and iridium‐catalyzed hydrogen borrowing cascade

A vinyl cyclopropane rearrangement embedded in an iridium‐catalyzed hydrogen borrowing reaction enabled the formation of substituted stereo‐defined cyclopentanes from Ph* methyl ketone and cyclopropyl alcohols. Mechanistic studies provide evidence for the ring‐expansion reaction being the result of...

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Main Authors: Wübbolt, S, Cheong, CB, Frost, JR, Christensen, KE, Donohoe, TJ
格式: Journal article
语言:English
出版: Wiley 2020