Bridging the gap between coordination and cluster compounds: unusual bonding modes for zinc.
Inner virtue: The reaction of [Mo(0)(GaCp*)(6)] with ZnMe(2) yields the novel multinuclear zinc system [MoZn(12)Me(9)Cp*(3)] which geometrically resembles a classical Wade-Mingos cluster (with an interstitial molybdenum atom, see picture). In reality, its electronic structure features little direct...
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Bibliographic Details
Main Authors: |
Kays, D,
Aldridge, S |
Format: | Journal article
|
Language: | English |
Published: |
2009
|