Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of furanyl (gamma)- and pyranyl (delta)-lactols.

Tetrahydropyran and tetrahydrofuran containing natural products, drugs and agrochemicals often possess carbon-carbon bonds adjacent to the heteroatom. Consequently, new methods for the construction of anomeric carbon-carbon bonds are of considerable importance. We have devised a new strategy to acce...

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Autori principali: Buffet, M, Dixon, D, Ley, S, Reynolds, D, Storer, R
Natura: Journal article
Lingua:English
Pubblicazione: 2004