Agostic interactions in alkyl derivatives of sterically hindered tris(pyrazolyl)borate complexes of niobium

This review describes how the joint experimental and computational study of a series of niobium(tris(pyrazolyl))(chloride)(alkyne)(alkyl) complexes has unearthed a very rich chemistry involving a variety of agostic interactions between the alkyl chain and the niobium centre. α and β C{single bond}H...

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Main Authors: Etienne, M, McGrady, J, Maseras, F
格式: Journal article
语言:English
出版: 2009