Gold-Catalyzed Diastereoselective Synthesis of alpha-Fluoroenones from Propargyl Acetates

Gold-Catalyzed Diastereoselective Synthesis of alpha-Fluoroenones from Propargyl Acetates

A diastereoselective preparation of -fluoroenones from propargyl acetates has been developed proceeding via a gold-catalyzed rearrangement-fluorination cascade. Control reactions are consistent with a mechanism involving a gold-mediated 3,3-sigmatropic shift followed by a direct, nongold-catalyzed e...

Полное описание

Библиографические подробности
Главные авторы:	Hopkinson, M, Giuffredi, G, Gee, A, Gouverneur, V
Формат:	Journal article
Язык:	English
Опубликовано:	2010

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