Scavenger templates: a systems chemistry approach to the synthesis of porphyrin-based molecular wires
A hexa-pyridyl template can be used as a scavenger to facilitate the synthesis of a linear porphyrin dodecamer from a mixture of linear hexamers with one or two terminal reactive groups. The template suppresses polymer formation by rapidly cyclizing the fully deprotected hexamer, thus upregulating f...
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| 格式: | Journal article |
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Royal Society of Chemistry
2017
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