AN INVERSE-PHOTOEMISSION STUDY OF EMPTY ELECTRONIC STATES IN TIO2
Empty electronic states in rutile (TiO2) have been studied by inverse photoemission spectroscopy at (110) and (001) surfaces. The spectra reveal a 2 eV splitting of the empty Ti 3d bands into π* and σ* components, with an overall Ti 3d bandwidth of order 6 eV. These values are in good agreement with...
Príomhchruthaitheoirí: | , , , , |
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Formáid: | Journal article |
Teanga: | English |
Foilsithe / Cruthaithe: |
1993
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Achoimre: | Empty electronic states in rutile (TiO2) have been studied by inverse photoemission spectroscopy at (110) and (001) surfaces. The spectra reveal a 2 eV splitting of the empty Ti 3d bands into π* and σ* components, with an overall Ti 3d bandwidth of order 6 eV. These values are in good agreement with periodic ab initio Hartree-Fock calculations. © 1993. |
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