A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond.
(Figure Presented) Hidden qualities: [Rh(PiPr3) (C 14H16)]-[BArF4] (1; see picture of the cation; P violet, Rh olive green), which was synthesized by treatment of [RhCl(nbd)-(PiPr3)] with Na[BArF4] (BAr F4 = B{C6H3-(CF3) 2}4) and norbornadiene (nbd) in fluorobenzene, contains an organic fragment der...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2006
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