Strained porphyrin tape–cycloparaphenylene hybrid nanorings
V-Shaped porphyrin dimers, with masked p-phenylene bridges, undergo efficient oxidative coupling to form meso-meso linked cyclic porphyrin oligomers. Reductive aromatization unmasks the p-phenylenes, increasing the strain. Oxidation then fuses the porphyrin dimers, providing a nanoring with curved w...
Main Authors: | , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2023
|