Strained porphyrin tape–cycloparaphenylene hybrid nanorings
V-Shaped porphyrin dimers, with masked p-phenylene bridges, undergo efficient oxidative coupling to form meso-meso linked cyclic porphyrin oligomers. Reductive aromatization unmasks the p-phenylenes, increasing the strain. Oxidation then fuses the porphyrin dimers, providing a nanoring with curved w...
Main Authors: | Stawski, W, Van Raden, JM, Patrick, CW, Horton, PN, Coles, SJ, Anderson, HL |
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Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2023
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