The complex superstructure in Mg1-xAlxB2 at x approximate to 0.5

Electron diffraction and high resolution microscopy have been performed on Mg1-xAlxB2 with x≅0.5. This composition displays a superstructure with a repeat period of exactly 2c along the c-axis and about 10 nm in the a-b plane. The superstructure results in ring-shaped superreflections in the diffrac...

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Main Authors: Zandbergen, H, Wu, M, Jiang, H, Hayward, M, Haas, M, Cava, R
Format: Journal article
Language:English
Published: 2002
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author Zandbergen, H
Wu, M
Jiang, H
Hayward, M
Haas, M
Cava, R
author_facet Zandbergen, H
Wu, M
Jiang, H
Hayward, M
Haas, M
Cava, R
author_sort Zandbergen, H
collection OXFORD
description Electron diffraction and high resolution microscopy have been performed on Mg1-xAlxB2 with x≅0.5. This composition displays a superstructure with a repeat period of exactly 2c along the c-axis and about 10 nm in the a-b plane. The superstructure results in ring-shaped superreflections in the diffraction pattern. Irradiation by a strong electron beam results in a loss of the superstructure and a decrease of about 1% in the c lattice parameter. In situ heating and cooling on the other hand showed that the superstructure is stable from 100 to 700 K. Possible origins for the superstructure are proposed. © 2002 Published by Elsevier Science B.V.
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spelling oxford-uuid:1500973a-cbf6-46f2-a847-2d400daa08222022-03-26T10:23:08ZThe complex superstructure in Mg1-xAlxB2 at x approximate to 0.5Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1500973a-cbf6-46f2-a847-2d400daa0822EnglishSymplectic Elements at Oxford2002Zandbergen, HWu, MJiang, HHayward, MHaas, MCava, RElectron diffraction and high resolution microscopy have been performed on Mg1-xAlxB2 with x≅0.5. This composition displays a superstructure with a repeat period of exactly 2c along the c-axis and about 10 nm in the a-b plane. The superstructure results in ring-shaped superreflections in the diffraction pattern. Irradiation by a strong electron beam results in a loss of the superstructure and a decrease of about 1% in the c lattice parameter. In situ heating and cooling on the other hand showed that the superstructure is stable from 100 to 700 K. Possible origins for the superstructure are proposed. © 2002 Published by Elsevier Science B.V.
spellingShingle Zandbergen, H
Wu, M
Jiang, H
Hayward, M
Haas, M
Cava, R
The complex superstructure in Mg1-xAlxB2 at x approximate to 0.5
title The complex superstructure in Mg1-xAlxB2 at x approximate to 0.5
title_full The complex superstructure in Mg1-xAlxB2 at x approximate to 0.5
title_fullStr The complex superstructure in Mg1-xAlxB2 at x approximate to 0.5
title_full_unstemmed The complex superstructure in Mg1-xAlxB2 at x approximate to 0.5
title_short The complex superstructure in Mg1-xAlxB2 at x approximate to 0.5
title_sort complex superstructure in mg1 xalxb2 at x approximate to 0 5
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