The role of phase in molecular Rydberg wave packet dynamics
The dynamics of Rydberg electron wave packets in a molecular system was investigated. Peaks in the autocorrelation function of a wave packet composed predominantly of two interleaved Rydberg series were observed at a stroboscopic period, which depends on both the difference in the ionization limits...
Những tác giả chính: | , , , , , |
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Định dạng: | Journal article |
Ngôn ngữ: | English |
Được phát hành: |
2003
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_version_ | 1826260434049564672 |
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author | Smith, R Stavros, V Verlet, J Fielding, H Townsend, D Softley, T |
author_facet | Smith, R Stavros, V Verlet, J Fielding, H Townsend, D Softley, T |
author_sort | Smith, R |
collection | OXFORD |
description | The dynamics of Rydberg electron wave packets in a molecular system was investigated. Peaks in the autocorrelation function of a wave packet composed predominantly of two interleaved Rydberg series were observed at a stroboscopic period, which depends on both the difference in the ionization limits of the two series, and on the quantum defects. This observation was rationalized by viewing the system as one in which two electron wave packets evolve independently until they overlap spatially. |
first_indexed | 2024-03-06T19:05:37Z |
format | Journal article |
id | oxford-uuid:15032fee-61b8-45f4-bbef-bc3aad01b07f |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T19:05:37Z |
publishDate | 2003 |
record_format | dspace |
spelling | oxford-uuid:15032fee-61b8-45f4-bbef-bc3aad01b07f2022-03-26T10:23:04ZThe role of phase in molecular Rydberg wave packet dynamicsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:15032fee-61b8-45f4-bbef-bc3aad01b07fEnglishSymplectic Elements at Oxford2003Smith, RStavros, VVerlet, JFielding, HTownsend, DSoftley, TThe dynamics of Rydberg electron wave packets in a molecular system was investigated. Peaks in the autocorrelation function of a wave packet composed predominantly of two interleaved Rydberg series were observed at a stroboscopic period, which depends on both the difference in the ionization limits of the two series, and on the quantum defects. This observation was rationalized by viewing the system as one in which two electron wave packets evolve independently until they overlap spatially. |
spellingShingle | Smith, R Stavros, V Verlet, J Fielding, H Townsend, D Softley, T The role of phase in molecular Rydberg wave packet dynamics |
title | The role of phase in molecular Rydberg wave packet dynamics |
title_full | The role of phase in molecular Rydberg wave packet dynamics |
title_fullStr | The role of phase in molecular Rydberg wave packet dynamics |
title_full_unstemmed | The role of phase in molecular Rydberg wave packet dynamics |
title_short | The role of phase in molecular Rydberg wave packet dynamics |
title_sort | role of phase in molecular rydberg wave packet dynamics |
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