Tuning affinity and reversibility for O2 binding in dinuclear Co(II) complexes.
The O2 binding affinity of a series of dicobalt(II) complexes can be tuned between p(O2)50% = 2.3 × 10(-3) and 700 × 10(-3) atm at 40 °C by varying the number of H and Cl atoms in the bridging acetato ligands of [Co2(bpbp)(CH(3-n)ClnCO2)(CH3CN)2](2+), where bpbp(-) = 2,6-bis(N,N-bis(2-pyridylmethyl)...
| Auteurs principaux: | , , , , , , , |
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| Format: | Journal article |
| Langue: | English |
| Publié: |
2013
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