Intercalation of catalytically active metal complexes in phyllosilicates and their application as propene polymerisation catalysts
The cationic Ziegler-Natta polymerisation catalyst [Zr(η-C5H5Me(thf)]+, is intercalated in a synthetic fluorinated mica-type silicate (NaMg2.5Si4O10F2) and the modified, swelling synthetic hectorite [LaponiteRD, Na0.46Mg5.42Li0.46Si8(OH) 4O20], by ion-exchange of [Zr(η-C5H5Me(thf)]+ ions with the in...
| Main Authors: | , , , |
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| Format: | Journal article |
| Published: |
1996
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