Global aromaticity in a partially fused 8-porphyrin nanoring

Template-directed synthesis has been used to prepare a fully π-conjugated cyclic porphyrin octamer, composed of both β,meso,β-edge-fused porphyrin tape units and butadiyne-linked porphyrins. The UV–vis–NIR spectra of this partially fused nanoring show that π-conjugation extends around the whole macr...

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Hlavní autoři: Kopp, SM, Gotfredsen, H, Deng, J-R, Claridge, TDW, Anderson, HL
Médium: Journal article
Jazyk:English
Vydáno: American Chemical Society 2020