Zn/Mn-MOFs with `S-shaped' packing modes.
Two novel polymers exhibiting metal-organic frameworks (MOFs) have been synthesized by the combination of a metal ion with a benzene-1,3,5-tricarboxylate ligand (BTC) and 1,10-phenanthroline (phen) under hydrothermal conditions. The first compound, poly[[(μ4-benzene-1,3,5-tricarboxylato-κ(4)O:O'...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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International Union of Crystallography
2014
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| _version_ | 1797055237123473408 |
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| author | Fan, H Xu, Q Ren, T Xing, X Christensen, K |
| author_facet | Fan, H Xu, Q Ren, T Xing, X Christensen, K |
| author_sort | Fan, H |
| collection | OXFORD |
| description | Two novel polymers exhibiting metal-organic frameworks (MOFs) have been synthesized by the combination of a metal ion with a benzene-1,3,5-tricarboxylate ligand (BTC) and 1,10-phenanthroline (phen) under hydrothermal conditions. The first compound, poly[[(μ4-benzene-1,3,5-tricarboxylato-κ(4)O:O':O'':O''')(μ-hydroxido-κ(2)O:O)bis(1,10-phenanthroline-κ(2)N,N')dizinc(II)] 0.32-hydrate], {[Zn2(C9H3O6)(OH)(C12H8N2)2]·0.32H2O}n, denoted Zn-MOF, forms a two-dimensional network in which a binuclear Zn2 cluster serves as a 3-connecting node; the BTC trianion also acts as a 3-connecting centre. The overall topology is that of a 6(3) net. The phen ligands serve as appendages to the network and interdigitate with phen ligands belonging to adjacent parallel sheets. The second compound, poly[[(μ6-benzene-1,3,5-tricarboxylato-κ(7)O(1),O(1'):O(1):O(3):O(3'):O(5):O(5'))(μ3-hydroxido-κ(2)O:O:O)(1,10-phenanthroline-κ(2)N,N')dimanganese(II)] 1.26-hydrate], {[Mn2(C9H3O6)(OH)(C12H8N2)]·1.26H2O}n, denoted Mn-MOF, exists as a three-dimensional network in which an Mn4 cluster serves as a 6-connecting unit, while the BTC trianion again plays the role of a 3-connecting centre. The overall topology is that of the rutile net. Phen ligands act as appendages to the network and form the `S-shaped' packing mode. |
| first_indexed | 2024-03-06T19:08:01Z |
| format | Journal article |
| id | oxford-uuid:15d2c5a6-e6ba-4354-8fcb-a7c74b29141f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:08:01Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | oxford-uuid:15d2c5a6-e6ba-4354-8fcb-a7c74b29141f2022-03-26T10:27:37ZZn/Mn-MOFs with `S-shaped' packing modes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:15d2c5a6-e6ba-4354-8fcb-a7c74b29141fEnglishSymplectic Elements at OxfordInternational Union of Crystallography2014Fan, HXu, QRen, TXing, XChristensen, KTwo novel polymers exhibiting metal-organic frameworks (MOFs) have been synthesized by the combination of a metal ion with a benzene-1,3,5-tricarboxylate ligand (BTC) and 1,10-phenanthroline (phen) under hydrothermal conditions. The first compound, poly[[(μ4-benzene-1,3,5-tricarboxylato-κ(4)O:O':O'':O''')(μ-hydroxido-κ(2)O:O)bis(1,10-phenanthroline-κ(2)N,N')dizinc(II)] 0.32-hydrate], {[Zn2(C9H3O6)(OH)(C12H8N2)2]·0.32H2O}n, denoted Zn-MOF, forms a two-dimensional network in which a binuclear Zn2 cluster serves as a 3-connecting node; the BTC trianion also acts as a 3-connecting centre. The overall topology is that of a 6(3) net. The phen ligands serve as appendages to the network and interdigitate with phen ligands belonging to adjacent parallel sheets. The second compound, poly[[(μ6-benzene-1,3,5-tricarboxylato-κ(7)O(1),O(1'):O(1):O(3):O(3'):O(5):O(5'))(μ3-hydroxido-κ(2)O:O:O)(1,10-phenanthroline-κ(2)N,N')dimanganese(II)] 1.26-hydrate], {[Mn2(C9H3O6)(OH)(C12H8N2)]·1.26H2O}n, denoted Mn-MOF, exists as a three-dimensional network in which an Mn4 cluster serves as a 6-connecting unit, while the BTC trianion again plays the role of a 3-connecting centre. The overall topology is that of the rutile net. Phen ligands act as appendages to the network and form the `S-shaped' packing mode. |
| spellingShingle | Fan, H Xu, Q Ren, T Xing, X Christensen, K Zn/Mn-MOFs with `S-shaped' packing modes. |
| title | Zn/Mn-MOFs with `S-shaped' packing modes. |
| title_full | Zn/Mn-MOFs with `S-shaped' packing modes. |
| title_fullStr | Zn/Mn-MOFs with `S-shaped' packing modes. |
| title_full_unstemmed | Zn/Mn-MOFs with `S-shaped' packing modes. |
| title_short | Zn/Mn-MOFs with `S-shaped' packing modes. |
| title_sort | zn mn mofs with s shaped packing modes |
| work_keys_str_mv | AT fanh znmnmofswithsshapedpackingmodes AT xuq znmnmofswithsshapedpackingmodes AT rent znmnmofswithsshapedpackingmodes AT xingx znmnmofswithsshapedpackingmodes AT christensenk znmnmofswithsshapedpackingmodes |