ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID
(S)-1-t-Butyl 4-methyl N-benzyloxycarbonylaspartate (5a), and (S)-1-t-butyl 4-allyl N-benzyloxycarbonylaspartate (5b) have been synthesized from (S)-aspartic acid (2), and can be readily alkylated and hydroxyalkylated at the β-carbon for asymmetric amino acid synthesis.
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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1989
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| _version_ | 1826260589669777408 |
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| author | Baldwin, J Moloney, M North, M |
| author_facet | Baldwin, J Moloney, M North, M |
| author_sort | Baldwin, J |
| collection | OXFORD |
| description | (S)-1-t-Butyl 4-methyl N-benzyloxycarbonylaspartate (5a), and (S)-1-t-butyl 4-allyl N-benzyloxycarbonylaspartate (5b) have been synthesized from (S)-aspartic acid (2), and can be readily alkylated and hydroxyalkylated at the β-carbon for asymmetric amino acid synthesis. |
| first_indexed | 2024-03-06T19:08:04Z |
| format | Journal article |
| id | oxford-uuid:15d55bc8-86b4-483c-a582-1029bdfa9278 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:08:04Z |
| publishDate | 1989 |
| record_format | dspace |
| spelling | oxford-uuid:15d55bc8-86b4-483c-a582-1029bdfa92782022-03-26T10:27:43ZASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACIDJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:15d55bc8-86b4-483c-a582-1029bdfa9278EnglishSymplectic Elements at Oxford1989Baldwin, JMoloney, MNorth, M(S)-1-t-Butyl 4-methyl N-benzyloxycarbonylaspartate (5a), and (S)-1-t-butyl 4-allyl N-benzyloxycarbonylaspartate (5b) have been synthesized from (S)-aspartic acid (2), and can be readily alkylated and hydroxyalkylated at the β-carbon for asymmetric amino acid synthesis. |
| spellingShingle | Baldwin, J Moloney, M North, M ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID |
| title | ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID |
| title_full | ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID |
| title_fullStr | ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID |
| title_full_unstemmed | ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID |
| title_short | ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID |
| title_sort | asymmetric amino acid synthesis preparation of the beta anion derived from aspartic acid |
| work_keys_str_mv | AT baldwinj asymmetricaminoacidsynthesispreparationofthebetaanionderivedfromasparticacid AT moloneym asymmetricaminoacidsynthesispreparationofthebetaanionderivedfromasparticacid AT northm asymmetricaminoacidsynthesispreparationofthebetaanionderivedfromasparticacid |