Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of lactols.
Treatment of alkynyl tributylstannane tetrahydropyranyl and tetrahydrofuranyl ether derivatives with boron trifluoride etherate effects an efficient anomeric oxygen to carbon rearrangement leading to the corresponding carbon-linked alkynol products.
| Glavni autori: | , , , |
|---|---|
| Format: | Journal article |
| Jezik: | English |
| Izdano: |
1998
|
| Sažetak: | Treatment of alkynyl tributylstannane tetrahydropyranyl and tetrahydrofuranyl ether derivatives with boron trifluoride etherate effects an efficient anomeric oxygen to carbon rearrangement leading to the corresponding carbon-linked alkynol products. |
|---|