Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of lactols.

Treatment of alkynyl tributylstannane tetrahydropyranyl and tetrahydrofuranyl ether derivatives with boron trifluoride etherate effects an efficient anomeric oxygen to carbon rearrangement leading to the corresponding carbon-linked alkynol products.

Bibliografske podrobnosti
Main Authors:	Buffet, M, Dixon, D, Ley, S, Tate, E
Format:	Journal article
Jezik:	English
Izdano:	1998

Podobne knjige/članki

Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of furanyl (gamma)- and pyranyl (delta)-lactols.
od: Buffet, M, et al.
Izdano: (2004)

Diastereoselective anomeric oxygen to carbon rearrangements of silyl enol ether derivatives of lactols.
od: Dixon, D, et al.
Izdano: (1998)

A general C-glycosidation procedure via anomeric oxygen to carbon rearrangements of tetrahydropyranyl ether derivatives
od: Buffet, M, et al.
Izdano: (1997)

A total synthesis of (+)-Goniodiol using an anomeric oxygen-to-carbon rearrangement
od: Dixon, D, et al.
Izdano: (1998)

Oxygen to carbon rearrangements of anomerically linked alkenols from tetrahydropyran derivatives: an investigation of the reaction mechanism via a double isotopic labelling crossover study
od: Buffet, M, et al.
Izdano: (2000)

Highly cis- or trans-selective oxygen to carbon rearrangements of anomerically linked 6-substituted tetrahydropyranyl enol ethers
od: Dixon, D, et al.
Izdano: (1999)

Diastereoselective oxygen to carbon rearrangements of anomerically linked enol ethers and the total synthesis of (+)-(S,S)-(cis-6-methyltetrahydropyran-2-yl)acetic acid, a component of civet
od: Dixon, D, et al.
Izdano: (2000)

Ring contraction versus β-elimination in reactions of alkynyl-substituted bicyclic lactol esters with SmI2/Pd(0)
od: José M. Aurrecoechea, et al.
Izdano: (2000-05-01)

Allylation of lactol in water
od: Zheng, Mengxue, et al.
Izdano: (2025)

6-methyl delta-lactol derived chiral glycine equivalents for the asymmetric synthesis of protected alpha-amino amides
od: Dixon, D, et al.
Izdano: (2004)

Short asymmetric syntheses of bioactive beta-aryl ethanolamine derivatives via the highly diastereoselective delta lactol oxy-Michael addition
od: Buchanan, D, et al.
Izdano: (2004)

Origin of diastereocontrol in the oxy-Michael reactions of delta-lactol anions: a computational and experimental study.
od: Richardson, R, et al.
Izdano: (2008)

Isotopic labelling studies for a gold-catalysed skeletal rearrangement of alkynyl aziridines
od: Paul W. Davies, et al.
Izdano: (2011-06-01)

ANOMERIC SPIROHYDANTOINS OF MANNOFURANOSE - APPROACHES TO NOVEL ANOMERIC AMINO-ACIDS BY AN OXIDATIVE RING CONTRACTION
od: Burton, J, et al.
Izdano: (1993)

CamTHP*OH: a camphor-derived delta-lactol auxiliary for the effective desymmetrization of attached glycinamide residues. Asymmetric synthesis of alpha-amino carbonyl compounds.
od: Dixon, D, et al.
Izdano: (2004)

Highly diastereoselective oxy-Michael additions of enantiopure delta-lactol anions to nitroalkenes: asymmetric synthesis of 1,2-amino alcohols.
od: Adderley, N, et al.
Izdano: (2003)

SPIROCYCLIC PEPTIDES AT THE ANOMERIC POSITION OF MANNOFURANOSE
od: Estevez, J, et al.
Izdano: (1994)

Direct synthesis of anomeric tetrazolyl iminosugars from sugar-derived lactams
od: Michał M. Więcław, et al.
Izdano: (2021-01-01)

Anomeric specificity of D-xylose isomerase.
od: Collyer, C, et al.
Izdano: (1992)

SPIRODIKETOPIPERAZINES AT THE ANOMERIC POSITION OF MANNOPYRANOSE - NOVEL N-LINKED GLYCOPEPTIDES INCORPORATING AN ALPHA-AMINO-ACID AT THE ANOMERIC POSITION OF MANNOPYRANOSE
od: Estevez, J, et al.
Izdano: (1995)

Investigations of alkynylbenziodoxole derivatives for radical alkynylations in photoredox catalysis
od: Yue Pan, et al.
Izdano: (2018-05-01)

Carbohydrate-derived amino-alcohol ligands for asymmetric alkynylation of aldehydes.
od: Emmerson, D, et al.
Izdano: (2006)

MESO-ALKYNYL PORPHYRINS
od: Anderson, H
Izdano: (1992)

Mechanochemical synthesis of oxygenated alkynyl carbon materials with excellent Hg(II) adsorption performance from CaC2 and carbonates
od: Yingjie Li, et al.
Izdano: (2023-02-01)

Carbopeptoids: peptides and diketopiperazines incorporating the anomeric centre of mannopyranose
od: Long, D, et al.
Izdano: (2001)

Anomeric modification of carbohydrates using the Mitsunobu reaction
od: Julia Hain, et al.
Izdano: (2018-06-01)

Sensing the anomeric effect in a solvent-free environment.
od: Cocinero, E, et al.
Izdano: (2011)

Alkynyl Radicals, Myths and Realities
od: Amal Lakhal, et al.
Izdano: (2025-02-01)

Copper-catalyzed aerobic C-C bond cleavage of lactols with N-hydroxy phthalimide for synthesis of lactones
od: Tnay, Ya Lin, et al.
Izdano: (2015)

The synthesis of mono- and bicyclic ethers via acid catalysed ring-opening cyclisation of tetrahydropyranyl ether derivatives
od: Dixon, D, et al.
Izdano: (2000)

Mycothiol synthesis by an anomerization reaction through endocyclic cleavage
od: Shino Manabe, et al.
Izdano: (2016-02-01)

Regioselective alkynylation followed by Suzuki coupling of 2,4-dichloroquinoline: Synthesis of 2-alkynyl-4-arylquinolines
od: Ellanki A. Reddy, et al.
Izdano: (2009-07-01)

Gold-catalyzed, intramolecular, oxygen-transfer reactions of 2-alkynyl-1,5-diketones or 2-alkynyl-5-ketoesters: Scope, expansion, and mechanistic investigations on a new [4+2] cycloaddition
od: Liu, L, et al.
Izdano: (2011)

Gold-catalyzed, intramolecular, oxygen-transfer reactions of 2-alkynyl-1,5-diketones or 2-alkynyl-5-ketoesters: scope, expansion, and mechanistic investigations on a new [4+2] cycloaddition.
od: Liu, L, et al.
Izdano: (2011)

Synthesis of alkynyl-substituted camphor derivatives and their use in the preparation of paclitaxel-related compounds
od: M. Fernanda N. N. Carvalho, et al.
Izdano: (2017-06-01)

Bond Rearrangement Produces Oxygen from Carbon Dioxide
od: Kamal Kumar, et al.
Izdano: (2024-04-01)

Alkynylation of Aldehydes Initiated by Cathodic Reduction
od: Dr. Eisuke Sato, et al.
Izdano: (2024-01-01)

Role of geometrical relaxation in solution of simple molecules exhibiting anomeric effects
od: Marcos, E, et al.
Izdano: (1996)

Biological Activity of NHC-Gold-Alkynyl Complexes Derived from 3-Hydroxyflavones
od: Inés Mármol, et al.
Izdano: (2022-09-01)

Effect of uridine protecting groups on the diastereoselectivity of uridine-derived aldehyde 5’-alkynylation
od: Raja Ben Othman, et al.
Izdano: (2017-08-01)