Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6](-) (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts
The synthesis of rhodium phosphine complexes partnered with carborane monoanions was reported. These complexes were evaluated as alkene hydrogenation catalysts. It was demonstrated that changing the counterion within the domain of closo-monocarboranes can have a significant effect on the efficiency...
Main Authors: | Rifat, A, Patmore, N, Mahon, M, Weller, A |
---|---|
格式: | Journal article |
语言: | English |
出版: |
2002
|
相似书籍
-
Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes.
由: Molinos, E, et al.
出版: (2007) -
Bi- and tri-metallic {Cp*RhCl} fragments partnered with carborane monoanions [CB11H6Y6](-) (Y = H, Br): control of nuclearity by choice of anion
由: Patmore, N, et al.
出版: (2003) -
Silver-phosphine complexes of the highly methylated carborane monoanion [closo-1-H-CB11Me11]-.
由: Clarke, A, et al.
出版: (2004) -
Investigation of the synthesis of {Mo(eta(5)-C5H5)(CO)(3)}(+) fragments partnered with the monoanionic carboranes [closo-CB11H11Br](-), [closo-CB11H6Br6](-) and [closo-HCB11Me11](-) by silver salt metathesis and hydride abstraction
由: Patmore, N, et al.
出版: (2003) -
The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.
由: Moxham, G, et al.
出版: (2006)