A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.
(Chemical Equation Presented) Top of the P-O-Ps: Stabilization of a cationic rhodium catalyst with the hemilabile P-O-P ligand dpephos allows efficient intermolecular hydroacylation of challenging substrates (see scheme). Structural studies have established the role of the coordination of the oxygen...
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Bibliographic Details
Main Authors: |
Moxham, G,
Randell-Sly, H,
Brayshaw, S,
Woodward, R,
Weller, A,
Willis, M |
Format: | Journal article
|
Language: | English |
Published: |
2006
|