A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.
(Chemical Equation Presented) Top of the P-O-Ps: Stabilization of a cationic rhodium catalyst with the hemilabile P-O-P ligand dpephos allows efficient intermolecular hydroacylation of challenging substrates (see scheme). Structural studies have established the role of the coordination of the oxygen...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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2006
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| _version_ | 1797055394861809664 |
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| author | Moxham, G Randell-Sly, H Brayshaw, S Woodward, R Weller, A Willis, M |
| author_facet | Moxham, G Randell-Sly, H Brayshaw, S Woodward, R Weller, A Willis, M |
| author_sort | Moxham, G |
| collection | OXFORD |
| description | (Chemical Equation Presented) Top of the P-O-Ps: Stabilization of a cationic rhodium catalyst with the hemilabile P-O-P ligand dpephos allows efficient intermolecular hydroacylation of challenging substrates (see scheme). Structural studies have established the role of the coordination of the oxygen atom, and a catalytically competent acylhydridorhodium intermediate was fully characterized. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-06T19:10:06Z |
| format | Journal article |
| id | oxford-uuid:1676effc-6feb-4700-98f3-f75f138ee727 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:10:06Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:1676effc-6feb-4700-98f3-f75f138ee7272022-03-26T10:31:32ZA second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1676effc-6feb-4700-98f3-f75f138ee727EnglishSymplectic Elements at Oxford2006Moxham, GRandell-Sly, HBrayshaw, SWoodward, RWeller, AWillis, M(Chemical Equation Presented) Top of the P-O-Ps: Stabilization of a cationic rhodium catalyst with the hemilabile P-O-P ligand dpephos allows efficient intermolecular hydroacylation of challenging substrates (see scheme). Structural studies have established the role of the coordination of the oxygen atom, and a catalytically competent acylhydridorhodium intermediate was fully characterized. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Moxham, G Randell-Sly, H Brayshaw, S Woodward, R Weller, A Willis, M A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. |
| title | A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. |
| title_full | A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. |
| title_fullStr | A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. |
| title_full_unstemmed | A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. |
| title_short | A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. |
| title_sort | second generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta s substituted aldehydes the role of a hemilabile p o p ligand |
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