Structural characterisation of a diprotonated ligand lanthanide complex--a key intermediate in lanthanide ion association and complex dissociation pathways.
The X-ray structure is reported of a diprotonated Gd(III) tetra-aqua complex of the ligand 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (DOTAM), a thermodynamic intermediate in metal ion association and dissociation pathways.
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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| Summary: | The X-ray structure is reported of a diprotonated Gd(III) tetra-aqua complex of the ligand 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (DOTAM), a thermodynamic intermediate in metal ion association and dissociation pathways. |
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