Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles
A thin film containing silica encapsulated face-centered tetragonal FePt nanoparticles was synthesized by using sequential nanochemistry preparation techniques. The silica coating offered the alloy particles a physical barrier against sintering by modifying their diffusion rates and surface energies...
Główni autorzy: | , , , , |
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Format: | Journal article |
Język: | English |
Wydane: |
2006
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_version_ | 1826261101896007680 |
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author | Yu, C Caiulo, N Lo, C Tam, K Tsang, S |
author_facet | Yu, C Caiulo, N Lo, C Tam, K Tsang, S |
author_sort | Yu, C |
collection | OXFORD |
description | A thin film containing silica encapsulated face-centered tetragonal FePt nanoparticles was synthesized by using sequential nanochemistry preparation techniques. The silica coating offered the alloy particles a physical barrier against sintering by modifying their diffusion rates and surface energies during the high-temperature annealing required for the fct phase transition. It was found that each quasi-spherical silica particle embracing the FePt can undergo self-assembly into a closely packed, ordered 2D array structure with identical interparticle spacing on a thin supporting film. A strong chemical attachment of the silica nanosphere to the oxide film was evident through a surface dehydroxylation reaction. A Langmuir-Blodgett (LB) deposition technique to control the arrangement of the silica encapsulated FePt on a substrate was carried out, followed by a high-temperature heat treatment and the heat-treated, silica-encapsulated sample displays magnetic hysteresis. |
first_indexed | 2024-03-06T19:16:17Z |
format | Journal article |
id | oxford-uuid:187cda0c-7d0c-4e96-9a8c-7db40d6eb421 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T19:16:17Z |
publishDate | 2006 |
record_format | dspace |
spelling | oxford-uuid:187cda0c-7d0c-4e96-9a8c-7db40d6eb4212022-03-26T10:43:35ZSynthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticlesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:187cda0c-7d0c-4e96-9a8c-7db40d6eb421EnglishSymplectic Elements at Oxford2006Yu, CCaiulo, NLo, CTam, KTsang, SA thin film containing silica encapsulated face-centered tetragonal FePt nanoparticles was synthesized by using sequential nanochemistry preparation techniques. The silica coating offered the alloy particles a physical barrier against sintering by modifying their diffusion rates and surface energies during the high-temperature annealing required for the fct phase transition. It was found that each quasi-spherical silica particle embracing the FePt can undergo self-assembly into a closely packed, ordered 2D array structure with identical interparticle spacing on a thin supporting film. A strong chemical attachment of the silica nanosphere to the oxide film was evident through a surface dehydroxylation reaction. A Langmuir-Blodgett (LB) deposition technique to control the arrangement of the silica encapsulated FePt on a substrate was carried out, followed by a high-temperature heat treatment and the heat-treated, silica-encapsulated sample displays magnetic hysteresis. |
spellingShingle | Yu, C Caiulo, N Lo, C Tam, K Tsang, S Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles |
title | Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles |
title_full | Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles |
title_fullStr | Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles |
title_full_unstemmed | Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles |
title_short | Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles |
title_sort | synthesis and fabrication of a thin film containing silica encapsulated face centered tetragonal fept nanoparticles |
work_keys_str_mv | AT yuc synthesisandfabricationofathinfilmcontainingsilicaencapsulatedfacecenteredtetragonalfeptnanoparticles AT caiulon synthesisandfabricationofathinfilmcontainingsilicaencapsulatedfacecenteredtetragonalfeptnanoparticles AT loc synthesisandfabricationofathinfilmcontainingsilicaencapsulatedfacecenteredtetragonalfeptnanoparticles AT tamk synthesisandfabricationofathinfilmcontainingsilicaencapsulatedfacecenteredtetragonalfeptnanoparticles AT tsangs synthesisandfabricationofathinfilmcontainingsilicaencapsulatedfacecenteredtetragonalfeptnanoparticles |