ANFO vapour detection with conducting polymer percolation network sensors and GC/MS

Ammonium nitrate mixed with fuel oil (ANFO) is commonly used in improvised explosive devices (IEDs). The development of ANFO vapour sensors that are small, inexpensive, and easy to use will enable widespread IED detection in the context of security and humanitarian demining. Because of concealment a...

Full description

Bibliographic Details
Main Authors: Lefferts, MJ, Humphreys, LH, Mai, N, Murugappan, K, Armitage, BI, Pons, J-F, Castell, MR
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2021
_version_ 1826261323309121536
author Lefferts, MJ
Humphreys, LH
Mai, N
Murugappan, K
Armitage, BI
Pons, J-F
Castell, MR
author_facet Lefferts, MJ
Humphreys, LH
Mai, N
Murugappan, K
Armitage, BI
Pons, J-F
Castell, MR
author_sort Lefferts, MJ
collection OXFORD
description Ammonium nitrate mixed with fuel oil (ANFO) is commonly used in improvised explosive devices (IEDs). The development of ANFO vapour sensors that are small, inexpensive, and easy to use will enable widespread IED detection in the context of security and humanitarian demining. Because of concealment and the low vapour pressures of most explosive materials, achieving sufficiently high sensitivity and low limits of detection are some of the main challenges of explosives vapour detection. Here ANFO chemiresistive vapour sensors based on polypyrrole (PPy) percolation networks are presented and compared to gas chromatography-mass spectroscopy (GC/MS) results for ANFO. Improved sensitivities are achieved by using a polymer percolation network instead of a thin film for the gas sensors. Vapour concentrations are detected of 13–180 ppb of ammonia emitted by a variety of different ammonium nitrate-containing fertilisers and fertiliser-diesel mixtures.
first_indexed 2024-03-06T19:19:35Z
format Journal article
id oxford-uuid:199e5702-31a2-4e5d-9b54-54f549bff9a6
institution University of Oxford
language English
last_indexed 2024-03-06T19:19:35Z
publishDate 2021
publisher Royal Society of Chemistry
record_format dspace
spelling oxford-uuid:199e5702-31a2-4e5d-9b54-54f549bff9a62022-03-26T10:49:57ZANFO vapour detection with conducting polymer percolation network sensors and GC/MSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:199e5702-31a2-4e5d-9b54-54f549bff9a6EnglishSymplectic ElementsRoyal Society of Chemistry2021Lefferts, MJHumphreys, LHMai, NMurugappan, KArmitage, BIPons, J-FCastell, MRAmmonium nitrate mixed with fuel oil (ANFO) is commonly used in improvised explosive devices (IEDs). The development of ANFO vapour sensors that are small, inexpensive, and easy to use will enable widespread IED detection in the context of security and humanitarian demining. Because of concealment and the low vapour pressures of most explosive materials, achieving sufficiently high sensitivity and low limits of detection are some of the main challenges of explosives vapour detection. Here ANFO chemiresistive vapour sensors based on polypyrrole (PPy) percolation networks are presented and compared to gas chromatography-mass spectroscopy (GC/MS) results for ANFO. Improved sensitivities are achieved by using a polymer percolation network instead of a thin film for the gas sensors. Vapour concentrations are detected of 13–180 ppb of ammonia emitted by a variety of different ammonium nitrate-containing fertilisers and fertiliser-diesel mixtures.
spellingShingle Lefferts, MJ
Humphreys, LH
Mai, N
Murugappan, K
Armitage, BI
Pons, J-F
Castell, MR
ANFO vapour detection with conducting polymer percolation network sensors and GC/MS
title ANFO vapour detection with conducting polymer percolation network sensors and GC/MS
title_full ANFO vapour detection with conducting polymer percolation network sensors and GC/MS
title_fullStr ANFO vapour detection with conducting polymer percolation network sensors and GC/MS
title_full_unstemmed ANFO vapour detection with conducting polymer percolation network sensors and GC/MS
title_short ANFO vapour detection with conducting polymer percolation network sensors and GC/MS
title_sort anfo vapour detection with conducting polymer percolation network sensors and gc ms
work_keys_str_mv AT leffertsmj anfovapourdetectionwithconductingpolymerpercolationnetworksensorsandgcms
AT humphreyslh anfovapourdetectionwithconductingpolymerpercolationnetworksensorsandgcms
AT main anfovapourdetectionwithconductingpolymerpercolationnetworksensorsandgcms
AT murugappank anfovapourdetectionwithconductingpolymerpercolationnetworksensorsandgcms
AT armitagebi anfovapourdetectionwithconductingpolymerpercolationnetworksensorsandgcms
AT ponsjf anfovapourdetectionwithconductingpolymerpercolationnetworksensorsandgcms
AT castellmr anfovapourdetectionwithconductingpolymerpercolationnetworksensorsandgcms