Carboboration of isocyanates with tris(pentafluorophenyl)borane and evidence for dissociative FLP chemistry of an acid–base pair

<p>We report on the reactivity of isocyanates towards tris(pentafluorophenyl)borane which was found to result in the 1,2-carboboration of the isocyanate C=O bond. The resulting six-membered heterocyclic compounds can be rationalized as adducts of imino-boranes with isocyanates and react accord...

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Hlavní autoři: Mehta, M, Goicoechea, J
Médium: Journal article
Jazyk:English
Vydáno: Royal Society of Chemistry 2019