Carboboration of isocyanates with tris(pentafluorophenyl)borane and evidence for dissociative FLP chemistry of an acid–base pair

<p>We report on the reactivity of isocyanates towards tris(pentafluorophenyl)borane which was found to result in the 1,2-carboboration of the isocyanate C=O bond. The resulting six-membered heterocyclic compounds can be rationalized as adducts of imino-boranes with isocyanates and react accord...

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Main Authors: Mehta, M, Goicoechea, J
格式: Journal article
语言:English
出版: Royal Society of Chemistry 2019