The influence of reaction-induced thermal convection on the electrical currents measured in chronoamperometry and cyclic voltammetry
Electrochemical reactions invariably occur with a change in the molar volume between reactant and product, as well as a change in enthalpy. These factors give rise to convective flows driven respectively by concentration and temperature and affect the mass transport in the system, but the latter has...
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| Médium: | Journal article |
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American Chemical Society
2016
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