The influence of reaction-induced thermal convection on the electrical currents measured in chronoamperometry and cyclic voltammetry
Electrochemical reactions invariably occur with a change in the molar volume between reactant and product, as well as a change in enthalpy. These factors give rise to convective flows driven respectively by concentration and temperature and affect the mass transport in the system, but the latter has...
Những tác giả chính: | , , |
---|---|
Định dạng: | Journal article |
Được phát hành: |
American Chemical Society
2016
|