A Study of the Catalytic Oxidative Oligomerization of Methane to Aromatics
The formation of aromatics during the reaction between methane and oxygen between 970 and 1220K, at elevated pressure has been studied. High selectivities and yields of the aromatics, i. e. benzene and toluene, are obtained over certain oxide catalysts, although, aromatics are also formed when no ca...
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Format: | Journal article |
Language: | English |
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1994
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author | York, A Claridge, J Green, M Tsang, S |
author_facet | York, A Claridge, J Green, M Tsang, S |
author_sort | York, A |
collection | OXFORD |
description | The formation of aromatics during the reaction between methane and oxygen between 970 and 1220K, at elevated pressure has been studied. High selectivities and yields of the aromatics, i. e. benzene and toluene, are obtained over certain oxide catalysts, although, aromatics are also formed when no catalyst is present. A manganese oxide catalyst doped with sodium chloride gave the highest yield of aromatics, however, supported nickel or platinum catalysts, which have been reported to be active catalysts for aromatics formation, were found to give lower yields of aromatics than for the gas-phase reaction. The mechanism for the production of aromatics has been investigated. © 1994 Elsevier Science B.V. All rights reserved. |
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format | Journal article |
id | oxford-uuid:1dd07647-b552-4744-9613-e52c7feed686 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T19:32:08Z |
publishDate | 1994 |
record_format | dspace |
spelling | oxford-uuid:1dd07647-b552-4744-9613-e52c7feed6862022-03-26T11:13:00ZA Study of the Catalytic Oxidative Oligomerization of Methane to AromaticsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1dd07647-b552-4744-9613-e52c7feed686EnglishSymplectic Elements at Oxford1994York, AClaridge, JGreen, MTsang, SThe formation of aromatics during the reaction between methane and oxygen between 970 and 1220K, at elevated pressure has been studied. High selectivities and yields of the aromatics, i. e. benzene and toluene, are obtained over certain oxide catalysts, although, aromatics are also formed when no catalyst is present. A manganese oxide catalyst doped with sodium chloride gave the highest yield of aromatics, however, supported nickel or platinum catalysts, which have been reported to be active catalysts for aromatics formation, were found to give lower yields of aromatics than for the gas-phase reaction. The mechanism for the production of aromatics has been investigated. © 1994 Elsevier Science B.V. All rights reserved. |
spellingShingle | York, A Claridge, J Green, M Tsang, S A Study of the Catalytic Oxidative Oligomerization of Methane to Aromatics |
title | A Study of the Catalytic Oxidative Oligomerization of Methane to Aromatics |
title_full | A Study of the Catalytic Oxidative Oligomerization of Methane to Aromatics |
title_fullStr | A Study of the Catalytic Oxidative Oligomerization of Methane to Aromatics |
title_full_unstemmed | A Study of the Catalytic Oxidative Oligomerization of Methane to Aromatics |
title_short | A Study of the Catalytic Oxidative Oligomerization of Methane to Aromatics |
title_sort | study of the catalytic oxidative oligomerization of methane to aromatics |
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