Bulk-mediated diffusion on a planar surface: Full solution

We consider the effective surface motion of a particle that intermittently unbinds from a planar surface and performs bulk excursions. Based on a random-walk approach, we derive the diffusion equations for surface and bulk diffusion including the surface-bulk coupling. From these exact dynamic equat...

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Bibliografski detalji
Glavni autori: Chechkin, A, Zaid, I, Lomholt, M, Sokolov, I, Metzler, R
Format: Journal article
Jezik:English
Izdano: 2012
Opis
Sažetak:We consider the effective surface motion of a particle that intermittently unbinds from a planar surface and performs bulk excursions. Based on a random-walk approach, we derive the diffusion equations for surface and bulk diffusion including the surface-bulk coupling. From these exact dynamic equations, we analytically obtain the propagator of the effective surface motion. This approach allows us to deduce a superdiffusive, Cauchy-type behavior on the surface, together with exact cutoffs limiting the Cauchy form. Moreover, we study the long-time dynamics for the surface motion. © 2012 American Physical Society.