Detecting mechanochemical atropisomerization within an STM break junction.

Detecting mechanochemical atropisomerization within an STM break junction.

We have employed the scanning tunneling microscope break-junction technique to investigate the single-molecule conductance of a family of 5,15-diaryl porphyrins bearing thioacetyl (SAc) or methylsulfide (SMe) binding groups at the ortho position of the phenyl rings (S2 compounds). These ortho substi...

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Bibliographic Details
Main Authors: Leary, E, Roche, C, Jiang, H, Grace, I, González, M, Rubio-Bollinger, G, Romero-Muñiz, C, Xiong, Y, Al-Galiby, Q, Noori, M, Lebedeva, M, Porfyrakis, K, Agrait, N, Hodgson, A, Higgins, S, Lambert, C, Anderson, H, Nichols, R
Format: Journal article
Language:English
Published: American Chemical Society 2017

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