Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid
The mechanisms for the electrodeposition and stripping of Zn 2+|Zn in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid are investigated via cyclic voltammetry. Analysis showed that the deposition of Zn onto a bulk Zn surface occurred via a two-electron process, with t...
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Format: | Journal article |
Language: | English |
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2012
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author | Ernst, S Henstridge, M Compton, R |
author_facet | Ernst, S Henstridge, M Compton, R |
author_sort | Ernst, S |
collection | OXFORD |
description | The mechanisms for the electrodeposition and stripping of Zn 2+|Zn in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid are investigated via cyclic voltammetry. Analysis showed that the deposition of Zn onto a bulk Zn surface occurred via a two-electron process, with the first electron transfer being rate determining. The electrodissolution was found to occur via a potentialdependent mechanism with the first electron transfer being rate determining near the formal potential, while an intermediate chemical step became rate determining at more positive potentials. © Springer-Verlag 2012. |
first_indexed | 2024-03-06T19:35:44Z |
format | Journal article |
id | oxford-uuid:1efa8ac3-3488-4b41-808b-bab83f0a1e35 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T19:35:44Z |
publishDate | 2012 |
record_format | dspace |
spelling | oxford-uuid:1efa8ac3-3488-4b41-808b-bab83f0a1e352022-03-26T11:19:19ZSwitching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquidJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1efa8ac3-3488-4b41-808b-bab83f0a1e35EnglishSymplectic Elements at Oxford2012Ernst, SHenstridge, MCompton, RThe mechanisms for the electrodeposition and stripping of Zn 2+|Zn in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid are investigated via cyclic voltammetry. Analysis showed that the deposition of Zn onto a bulk Zn surface occurred via a two-electron process, with the first electron transfer being rate determining. The electrodissolution was found to occur via a potentialdependent mechanism with the first electron transfer being rate determining near the formal potential, while an intermediate chemical step became rate determining at more positive potentials. © Springer-Verlag 2012. |
spellingShingle | Ernst, S Henstridge, M Compton, R Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
title | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
title_full | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
title_fullStr | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
title_full_unstemmed | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
title_short | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
title_sort | switching transition states with changing electrode potential zn ii zn electrodeposition on glassy carbon in the n butyl n methylpyrrolidinium bis trifluoromethylsulfonyl imide ionic liquid |
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