Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid
The mechanisms for the electrodeposition and stripping of Zn 2+|Zn in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid are investigated via cyclic voltammetry. Analysis showed that the deposition of Zn onto a bulk Zn surface occurred via a two-electron process, with t...
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| Format: | Journal article |
| Language: | English |
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2012
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| _version_ | 1797057395817447424 |
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| author | Ernst, S Henstridge, M Compton, R |
| author_facet | Ernst, S Henstridge, M Compton, R |
| author_sort | Ernst, S |
| collection | OXFORD |
| description | The mechanisms for the electrodeposition and stripping of Zn 2+|Zn in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid are investigated via cyclic voltammetry. Analysis showed that the deposition of Zn onto a bulk Zn surface occurred via a two-electron process, with the first electron transfer being rate determining. The electrodissolution was found to occur via a potentialdependent mechanism with the first electron transfer being rate determining near the formal potential, while an intermediate chemical step became rate determining at more positive potentials. © Springer-Verlag 2012. |
| first_indexed | 2024-03-06T19:35:44Z |
| format | Journal article |
| id | oxford-uuid:1efa8ac3-3488-4b41-808b-bab83f0a1e35 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:35:44Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:1efa8ac3-3488-4b41-808b-bab83f0a1e352022-03-26T11:19:19ZSwitching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquidJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1efa8ac3-3488-4b41-808b-bab83f0a1e35EnglishSymplectic Elements at Oxford2012Ernst, SHenstridge, MCompton, RThe mechanisms for the electrodeposition and stripping of Zn 2+|Zn in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid are investigated via cyclic voltammetry. Analysis showed that the deposition of Zn onto a bulk Zn surface occurred via a two-electron process, with the first electron transfer being rate determining. The electrodissolution was found to occur via a potentialdependent mechanism with the first electron transfer being rate determining near the formal potential, while an intermediate chemical step became rate determining at more positive potentials. © Springer-Verlag 2012. |
| spellingShingle | Ernst, S Henstridge, M Compton, R Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
| title | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
| title_full | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
| title_fullStr | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
| title_full_unstemmed | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
| title_short | Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid |
| title_sort | switching transition states with changing electrode potential zn ii zn electrodeposition on glassy carbon in the n butyl n methylpyrrolidinium bis trifluoromethylsulfonyl imide ionic liquid |
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