Experimental cyclic voltammetry at partially blocked electrodes: Elevated cylindrical blocks - Significantly blocked and non-flat electrodes can appear to show one-dimensional diffusion

The cyclic voltammetric response of planar electrodes modified with cylindrical blocks is modeled using finite difference simulations. The validity of the simulation approach employed is verified using experimental data obtained from partially blocked gold electrodes. Comparison of theory with exper...

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Bibliographic Details
Main Authors: Chevallier, F, Fietkau, N, del Campo, J, Mas, R, Munoz, F, Jiang, L, Jones, T, Compton, R
Format: Journal article
Language:English
Published: 2006