Atomic level spatial variations of energy states along graphene edges
The local atomic bonding of carbon atoms around the edge of graphene is examined by aberration-corrected scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). High-resolution 2D maps of the EELS combined with atomic resolution annular dark field STE...
Main Authors: | , , , , |
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Formato: | Journal article |
Idioma: | English |
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American Chemical Society
2014
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_version_ | 1826262735113945088 |
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author | Warner, J Lin, Y He, K Koshino, M Suenaga, K |
author_facet | Warner, J Lin, Y He, K Koshino, M Suenaga, K |
author_sort | Warner, J |
collection | OXFORD |
description | The local atomic bonding of carbon atoms around the edge of graphene is examined by aberration-corrected scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). High-resolution 2D maps of the EELS combined with atomic resolution annular dark field STEM images enables correlations between the carbon K-edge EELS and the atomic structure. We show that energy states of graphene edges vary across individual atoms along the edge according to their specific C-C bonding, as well as perpendicular to the edge. Unique spectroscopic peaks from the EELS are assigned to specific C atoms, which enables unambiguous spectroscopic fingerprint identification for the atomic structure of graphene edges with unprecedented detail. |
first_indexed | 2024-03-06T19:40:46Z |
format | Journal article |
id | oxford-uuid:209a37e5-1d23-4777-a176-d02fec186df1 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T19:40:46Z |
publishDate | 2014 |
publisher | American Chemical Society |
record_format | dspace |
spelling | oxford-uuid:209a37e5-1d23-4777-a176-d02fec186df12022-03-26T11:28:25ZAtomic level spatial variations of energy states along graphene edgesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:209a37e5-1d23-4777-a176-d02fec186df1EnglishSymplectic Elements at OxfordAmerican Chemical Society2014Warner, JLin, YHe, KKoshino, MSuenaga, KThe local atomic bonding of carbon atoms around the edge of graphene is examined by aberration-corrected scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). High-resolution 2D maps of the EELS combined with atomic resolution annular dark field STEM images enables correlations between the carbon K-edge EELS and the atomic structure. We show that energy states of graphene edges vary across individual atoms along the edge according to their specific C-C bonding, as well as perpendicular to the edge. Unique spectroscopic peaks from the EELS are assigned to specific C atoms, which enables unambiguous spectroscopic fingerprint identification for the atomic structure of graphene edges with unprecedented detail. |
spellingShingle | Warner, J Lin, Y He, K Koshino, M Suenaga, K Atomic level spatial variations of energy states along graphene edges |
title | Atomic level spatial variations of energy states along graphene edges |
title_full | Atomic level spatial variations of energy states along graphene edges |
title_fullStr | Atomic level spatial variations of energy states along graphene edges |
title_full_unstemmed | Atomic level spatial variations of energy states along graphene edges |
title_short | Atomic level spatial variations of energy states along graphene edges |
title_sort | atomic level spatial variations of energy states along graphene edges |
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