Atomic level spatial variations of energy states along graphene edges

The local atomic bonding of carbon atoms around the edge of graphene is examined by aberration-corrected scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). High-resolution 2D maps of the EELS combined with atomic resolution annular dark field STE...

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Main Authors: Warner, J, Lin, Y, He, K, Koshino, M, Suenaga, K
Formato: Journal article
Idioma:English
Publicado em: American Chemical Society 2014
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author Warner, J
Lin, Y
He, K
Koshino, M
Suenaga, K
author_facet Warner, J
Lin, Y
He, K
Koshino, M
Suenaga, K
author_sort Warner, J
collection OXFORD
description The local atomic bonding of carbon atoms around the edge of graphene is examined by aberration-corrected scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). High-resolution 2D maps of the EELS combined with atomic resolution annular dark field STEM images enables correlations between the carbon K-edge EELS and the atomic structure. We show that energy states of graphene edges vary across individual atoms along the edge according to their specific C-C bonding, as well as perpendicular to the edge. Unique spectroscopic peaks from the EELS are assigned to specific C atoms, which enables unambiguous spectroscopic fingerprint identification for the atomic structure of graphene edges with unprecedented detail.
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spelling oxford-uuid:209a37e5-1d23-4777-a176-d02fec186df12022-03-26T11:28:25ZAtomic level spatial variations of energy states along graphene edgesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:209a37e5-1d23-4777-a176-d02fec186df1EnglishSymplectic Elements at OxfordAmerican Chemical Society2014Warner, JLin, YHe, KKoshino, MSuenaga, KThe local atomic bonding of carbon atoms around the edge of graphene is examined by aberration-corrected scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). High-resolution 2D maps of the EELS combined with atomic resolution annular dark field STEM images enables correlations between the carbon K-edge EELS and the atomic structure. We show that energy states of graphene edges vary across individual atoms along the edge according to their specific C-C bonding, as well as perpendicular to the edge. Unique spectroscopic peaks from the EELS are assigned to specific C atoms, which enables unambiguous spectroscopic fingerprint identification for the atomic structure of graphene edges with unprecedented detail.
spellingShingle Warner, J
Lin, Y
He, K
Koshino, M
Suenaga, K
Atomic level spatial variations of energy states along graphene edges
title Atomic level spatial variations of energy states along graphene edges
title_full Atomic level spatial variations of energy states along graphene edges
title_fullStr Atomic level spatial variations of energy states along graphene edges
title_full_unstemmed Atomic level spatial variations of energy states along graphene edges
title_short Atomic level spatial variations of energy states along graphene edges
title_sort atomic level spatial variations of energy states along graphene edges
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AT liny atomiclevelspatialvariationsofenergystatesalonggrapheneedges
AT hek atomiclevelspatialvariationsofenergystatesalonggrapheneedges
AT koshinom atomiclevelspatialvariationsofenergystatesalonggrapheneedges
AT suenagak atomiclevelspatialvariationsofenergystatesalonggrapheneedges