Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials
Mechanistic studies on Cu-catalysed asymmetric additions of alkylzirconocene nucleophiles to racemic allylic halide electrophiles were conducted using a combination of isotopic labelling, NMR spectroscopy, kinetic modeling, structure-activity relationships and new reaction development. Kinetic and d...
Autors principals: | , , , , |
---|---|
Format: | Journal article |
Publicat: |
American Chemical Society
2017
|