2-C-Methyl-D-allono-1,4-lactone

The relative stereochemistry of the compound 2-c-methyl-D-allono-1,4-lactone was established using X ray crystallographic analysis. The absolute stereochemistry was defined by the use of D-ribonolactone as a starting material. All H atoms were observed in a difference electron density map and were r...

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Bibliografische gegevens
Hoofdauteurs: Harding, C, Watkin, D, Sawyer, N, Jenkinson, S, Fleet, G
Formaat: Journal article
Taal:English
Gepubliceerd in: 2005
Omschrijving
Samenvatting:The relative stereochemistry of the compound 2-c-methyl-D-allono-1,4-lactone was established using X ray crystallographic analysis. The absolute stereochemistry was defined by the use of D-ribonolactone as a starting material. All H atoms were observed in a difference electron density map and were refined using slack restraints to optimize their geometry. The crystal structure was made up of layers of strongly hydrogen-bonded molecules, which were found to be lying in the ab plane.