Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.
Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2015
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| _version_ | 1797057840191373312 |
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| author | Sidera, M Fletcher, S |
| author_facet | Sidera, M Fletcher, S |
| author_sort | Sidera, M |
| collection | OXFORD |
| description | Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products. |
| first_indexed | 2024-03-06T19:42:06Z |
| format | Journal article |
| id | oxford-uuid:210850ce-072c-4e77-8f4a-b636f54e480a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:42:06Z |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:210850ce-072c-4e77-8f4a-b636f54e480a2022-03-26T11:30:54ZCu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:210850ce-072c-4e77-8f4a-b636f54e480aEnglishSymplectic Elements at OxfordRoyal Society of Chemistry2015Sidera, MFletcher, SAlkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products. |
| spellingShingle | Sidera, M Fletcher, S Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides. |
| title | Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides. |
| title_full | Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides. |
| title_fullStr | Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides. |
| title_full_unstemmed | Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides. |
| title_short | Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides. |
| title_sort | cu catalyzed asymmetric addition of sp² hybridized zirconium nucleophiles to racemic allyl bromides |
| work_keys_str_mv | AT sideram cucatalyzedasymmetricadditionofsp2hybridizedzirconiumnucleophilestoracemicallylbromides AT fletchers cucatalyzedasymmetricadditionofsp2hybridizedzirconiumnucleophilestoracemicallylbromides |