Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide
A novel [18F]NF reagent and two novel radiochemical transformations have been developed: [18F]NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radi...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2007
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| _version_ | 1826262962127503360 |
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| author | Teare, H Robins, E Årstad, E Luthra, S Gouverneur, V |
| author_facet | Teare, H Robins, E Årstad, E Luthra, S Gouverneur, V |
| author_sort | Teare, H |
| collection | OXFORD |
| description | A novel [18F]NF reagent and two novel radiochemical transformations have been developed: [18F]NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radiosynthesis of the fluorinated A ring of vitamin D 3 has also been completed with success. © The Royal Society of Chemistry. |
| first_indexed | 2024-03-06T19:44:09Z |
| format | Journal article |
| id | oxford-uuid:21b0648e-c62e-4a35-9e52-fa511c8128d1 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:44:09Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:21b0648e-c62e-4a35-9e52-fa511c8128d12022-03-26T11:34:43ZSynthesis and reactivity of [18F]-N-fluorobenzenesulfonimideJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:21b0648e-c62e-4a35-9e52-fa511c8128d1EnglishSymplectic Elements at Oxford2007Teare, HRobins, EÅrstad, ELuthra, SGouverneur, VA novel [18F]NF reagent and two novel radiochemical transformations have been developed: [18F]NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radiosynthesis of the fluorinated A ring of vitamin D 3 has also been completed with success. © The Royal Society of Chemistry. |
| spellingShingle | Teare, H Robins, E Årstad, E Luthra, S Gouverneur, V Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide |
| title | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide |
| title_full | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide |
| title_fullStr | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide |
| title_full_unstemmed | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide |
| title_short | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide |
| title_sort | synthesis and reactivity of 18f n fluorobenzenesulfonimide |
| work_keys_str_mv | AT teareh synthesisandreactivityof18fnfluorobenzenesulfonimide AT robinse synthesisandreactivityof18fnfluorobenzenesulfonimide AT arstade synthesisandreactivityof18fnfluorobenzenesulfonimide AT luthras synthesisandreactivityof18fnfluorobenzenesulfonimide AT gouverneurv synthesisandreactivityof18fnfluorobenzenesulfonimide |