Diastereoselective anomeric oxygen to carbon rearrangements of silyl enol ether derivatives of lactols.

Lewis acid promoted oxygen to carbon rearrangement of anomerically linked silyl enol ethers gives a new and diastereoselective route to the corresponding 2-α-hydroxyketone substituted products.

Bibliographic Details
Main Authors: Dixon, D, Ley, S, Tate, E
Format: Journal article
Language:English
Published: 1998
Description
Summary:Lewis acid promoted oxygen to carbon rearrangement of anomerically linked silyl enol ethers gives a new and diastereoselective route to the corresponding 2-α-hydroxyketone substituted products.