Mechanistic aspects of the electrocatalytic oxidative cleavage of 1,2-diols by electrogenerated Pb(IV)

Mechanistic aspects of the electrocatalytic oxidative cleavage of 1,2-diols by electrogenerated Pb(IV)

The electrochemical oxidation of Pb(II) to Pb(IV) in acetonitrile solution containing benzoic acid and pyridine is possible at a basal-plane pyrolytic-graphite electrode and associated with a rapid ligand exchange at the metal center. The Pb(IV) species generated under these conditions is shown to r...

书目详细资料
Main Authors:	Marken, F, Squires, A, Alden, J, Compton, R, Buston, J, Moloney, M
格式:	Journal article
语言:	English
出版:	1998

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