Mechanistic aspects of the electrocatalytic oxidative cleavage of 1,2-diols by electrogenerated Pb(IV)
The electrochemical oxidation of Pb(II) to Pb(IV) in acetonitrile solution containing benzoic acid and pyridine is possible at a basal-plane pyrolytic-graphite electrode and associated with a rapid ligand exchange at the metal center. The Pb(IV) species generated under these conditions is shown to r...
| Autors principals: | , , , , , |
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| Format: | Journal article |
| Idioma: | English |
| Publicat: |
1998
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