Nickel(II)-catalyzed addition of aryl and heteroaryl boroxines to the sulfinylamine reagent TrNSO: the catalytic synthesis of sul-finamides, sulfonimidamides and primary sulfonamides
We report a redox-neutral Ni(II)-catalyzed addition of (hetero)aryl boroxines to N-sulfinyltritylamine (TrNSO). The reactions use a catalyst generated from the combination of commercial, air-stable NiCl2·(glyme) and a commercially available bipyridine ligand, and deliver sulfinamide products. The sc...
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| Médium: | Journal article |
| Jazyk: | English |
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American Chemical Society
2021
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